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Information leaflets

Understanding PT statistics

Word cloud - statistical terms

Content

WordCloudRect90rThe Eurachem Guide on “Selection, Use and Interpretation of Proficiency Testing (PT) Schemes” recommends participants to consider the statistical approach used by the PT provider when selecting a PT scheme. This leaflet is intended to help participants in quantitative PT schemes to better understand the statistical parameters that are used in the PT report to describe the distribution of results reported by participants.

Availability

The leaflet is currently available in English.

 

Translation

Please consult the PT Working Group Chair if you would like to prepare a translation in your own language.

 

Notes

1. Dates show date of publication of the linked file on this website.

 

Understanding PT performance assessment

Word cloud - statistical terms

Content

scorebasis 01All proficiency testing schemes include an assessment of laboratory performance. Most compare a laboratory result with an assigned value, and assess performance based on the difference and a criterion for successful performance. Often, this assessment also involves calculating a score for consistent interpretation across rounds and, sometimes, across PT schemes. But there are many different ways of determining an assigned value and setting a criterion for performance assessment, and there are several different scoring methods. 

This leaflet is intended to help participants in quantitative proficiency testing (PT) schemes to better understand the performance assessment made by the PT provider.

Availability

The leaflet is currently available in English.

 

Translation

Please consult the PT Working Group Chair if you would like to prepare a translation in your own language.

 

Notes

1. Dates show date of publication of the linked file on this website.

 

Information leaflets

pt-cmp-mrg132Eurachem Information Leaflets are short briefing documents on a specific topic. Information leaflets are usually intended to inform a wide audience, including laboratory staff, managers and laboratory customers.

Like Guides, Information Leaflets are developed by the different Working Groups, often in cooperation with other organisations.

Eurachem information leaflets are all available free of charge from the website. Many have been translated into several languages.

Current Eurachem Information Leaflets

The current list of topics and information leaflets is given below. All leaflets are available in English; availability in additional languages is indicated below. "Translations available" indicates that more than four language versions (including English) are available.

Previous editions, which may be available in additional languages, can be found in our publication archive.

Accreditation

Proficiency testing

Measurement uncertainty and traceability

Method validation

Terminology

Withdrawn and Superseded Information Leaflets

Some older Eurachem Information leaflets have been superseded by the current editions listed above or withdrawn as no longer of current interest. Available electronic copies of all superseded guidance are, however, listed in the Publication Archive for reference.

Interlaboratory comparisons other than proficiency testing

Content

wordcloud 200The international standard ISO/IEC 17025 requires a laboratory to participate in proficiency testing (PT) and/or to participate in interlaboratory comparisons (ILCs) other than PT. However, the Standard gives no guidance as to what these other ILCs might be, or indeed how they might compare in relation to PT.

This leaflet, prepared by the EEE-PT Working Group, outlines other types of interlaboratory comparison and points out some of the limitations as compared to PT.

Availability

Translation

Please consult the PT Working Group Chair if you would like to prepare a translation in your own language.

 

Notes

1. Publication dates are dates of website publication for the current version.

2. First published 2024-04-10. Current file version (Ed.1a) includes editorial correction to date of publication.

Let's call a PT scheme a PT scheme!

Content

Factors affecting PT strategy

Interlaboratory comparisons (ILCs) have been used for more than a century and many important concepts are linked to them.

This leaflet, prepared by the Eurachem PT Working Group, addresses the basic terminology of ILCs, explains why some colloquial terms can be misleading or misunderstood, and the importance of harmonisation..

Availability

Translation

Please consult the PT Working Group Chair if you would like to prepare a translation in your own language.

 

Notes

1. Publication dates are dates of website publication for the current version.

2. English version (V1) first published on this site on 2022-05-30. Amendment V1a (editorial amendment only) added 2022-07-29.

What is the uncertainty factor?

Content

Distribution of GMO results showing approximately lognormal distribution

Appropriate expression of the measurement uncertainty (MU) is crucial, and there are situations when the traditional, symmetric, expanded uncertainty interval is not sufficient. This leaflet aims to explain the concept of the uncertainty factor and how it can be used to provide a convenient and realistic uncertainty interval in particular circumstances..

This leaflet was produced by the Eurachem Sampling Uncertainty Working Group and the Royal Society of Chemistry Analytical Methods Committee (AMC) Sampling Uncertainty Working Groups.

Availability

Translation

Please consult the Eurachem Sampling Uncertainty Working Group Chair, directly or by using the UfSWG contact form, if you would like to prepare a translation in your own language.

 

*Publication dates are dates of website publication. English version first published on this site on 2020-07-29.

Use of uncertainty information in compliance (2021)

Content

Acceptance and rejection zones with a guard band used for high confidence of correct rejection ("Stringent Acceptance")This information leaflet is intended for laboratories perfoming chemical analyses. It has been prepared by the Eurachem Measurement Uncertainty and Tracability Working Group (see here for details) to introduce the use of decision rules and guard bands in interpreting results accompanied by measurement uncertainty information. The leaflet summarises the principles described in the Eurachem Guide "Use of uncertainty information in compliance assessment", which is available here.

This revised edition of this information leaflet is amended to reflect changes in the second edition of the compliance Guide.

Availability

 

* Publication dates are dates of publication on this website.

** First published 2021-09-01; amended 2021-12-09.

Translation

Translation into other languages is encouraged for members of Eurachem. Other offers of translation should be directed to the Eurachem Secretariat for permission. The Eurachem policy on maintenance and development of Eurachem guidance, available on the Policies page, gives further information on translation.

Note: The previous (2015) edition is available in English, Czech, Estonian, Finnish, Portuguese, Turkish and Ukrainian.

Previous editions

The previous edition of this leaflet can be found here.

The importance of method validation

Content

Factors affecting PT strategy

Method validation is an important requirement in the practice of analytical science. ISO/IEC 17025, OECD guidelines on Good Manufacturing Practice and many similar codes of practice require some level of validation, whether by verification of the laboratory's implementation of published standard methods, or by comprehensive validation studies of new, in-house, procedures. Most analytical chemists are aware of its importance, but why it should be done, when, and exactly what needs to be done, is not always clear.

This leaflet, prepared by the Eurachem Method Validation working group, gives a brief introduction to the overall process of validation and the key performance characteristics to be studied, and provides pointers to more detailed guidance.

Availability

Translation

Please consult the Method Validation Working Group if you would like to prepare a translation in your own language.

 

*Publication dates are dates of website publication. English version first published on this site on 2021-02-25.

Investigating poor performance in proficiency testing

Content

Factors affecting PT strategyA laboratory will occasionally have a poor performance in a PT scheme. When this occurs, the laboratory should acknowledge it, carry out an investigation and document a review of possible causes, even if it decides not to take any specific action. This leaflet, prepared by the EURACHEM Proficiency Testing Working Group, gives advice for laboratories on how to best address such events.

This second edition is an editorial amendment to reference recent guidance on proficiency testing.

Availability

The second edition is currently available in the following languages. Links to translations of the first edition, available in 10 languages, are temporarily maintained on this page (below) for convenience while translations of the second edition are prepared. 

Translation

Please consult the PT Working Group Chair if you would like to prepare a translation in your own language.

Previous editions

The first edition of this information leaflet can be found here, in our publication archive. Selected translations of the first edition are listed below for convenience pending translation of the second edition.

 

Notes

1. Dates show date of publication of the linked file on this website.

2. 2nd English edition first published 2022-07-30

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Proficiency testing schemes for sampling

Content

Factors affecting PT strategy

Proficiency Testing schemes for sampling play an important role in the improvement of sampling procedures and also in the development of participants from an educational point of view, especially if workshops with the participants are organised. PT schemes for sampling can also give an appreciation of the contribution of the sampling in relation to the overall quality of the measurement, including the associated contribution to the measurement uncertainty.

This leaflet, prepared by the EEE-PT Working Group, gives some hints on the application of ISO/IEC 17043 for PT providers organising PT schemes for sampling. If there is a comparison between participants and a mechanism for performance evaluation which meets the objective of the PT scheme for sampling, then ISO/IEC 17043 is applicable.

Availability

Translation

Please consult the PT Working Group Chair if you would like to prepare a translation in your own language.

 

Notes

1. Dates show date of publication of the linked file on this website.

2. 2nd English edition first published 2020-07-29

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